# Top-rated ScreenCasts

Text Section | Link to original post | Rating (out of 100) | Number of votes | Copy of rated post |
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17.12 Energy Balances for Reactions | Click here. | 20 | 1 |
Equilibrium constants and adiabatic reactor calculations with Excel (uakron.edu, 6 min) We previously discussed adiabatic reactor calculations in Section 3.6 with application to the dimethyl ether process. At that time, we accepted the expression for equilibrium constant as given. In Chapter 17, we must recognize how to compute the equilibrium constant for ourselves. This presentation illustrates the calculations for Example 17.9. These kinds of calculations often occur in the context of an overall process, rather than in isolation. Therefore, the presentation shows how to apply Eqn 3.5b with pathway 2.6c to characterize the enthalpies of process streams and solve for the extent of reaction and adiabatic outlet temperature simultaneously. Comprehension Questions: 1. Suppose the reactor inlet feed was: kmol/hr of 110 N2, 300 H2, 15NH3 and 16 CH4. Solve for the adiabatic reactor temperature and extent of reaction in that case. |

08.07 - Implementation of Departure Functions | Click here. | 20 | 5 |
Helmholtz Example - Modified vdW EOS (uakron.edu, 13min) A aρ/RT). Note that the limits of integration matter for this EOS. The audio is inferior for this live video, but it responds to typical questions and confusion from students in the audience. Some students might find it helpful to hear the kinds of questions that students ask. The responses slow the derivation down so that no steps are skipped and key steps are reiterated multiple times. Just turn the volume up!
Comprehension questions: 1. Which part of this EOS is non-zero at the zero density limit of integration? 2. Is there a sign error on one of the terms in this video? Check the derivation independently. 3. Derive the Helmholtz departure given Z = 1 + 4bρ/(1-bρ)2 - (9.5a)/{1ρ/RT-[1-4a/bRTb4ρ+2]}.
(bρ)4. Derive the Helmholtz departure given Z = 1 + 4bρ/(1-2bρ) - (9.5a){1+4ρ/RT[1-2aρ/bRT2]}/{1(bρ)-[1-4a/bRTb4ρ+2]})/{1(bρ)-[1-4a/bRTb4ρ+2]}(bρ) |