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|13.04 - UNIQUAC||Click here.||73.33329999999999||3||
UNIQUAC concepts (6:44) (msu.edu)
Concepts and assumptions used in developing the UNIQUAC activity coefficient method. This method introduced the use of surface area as an important quantity in calculation of activity coefficients.
|10.03 - Binary VLE using Raoult's Law||Click here.||73.33329999999999||3||
Raoult's Law Calculation Procedures (11:45) (msu.edu)
Comprehension Questions: Assume the ideal solution SCVP model (Eqns. 2.47 and 10.8).
1. Estimate the bubble pressure (bars) of 30% acetone + 70% benzene at 333K.
|07.05 Cubic Equations of State||Click here.||73.33329999999999||3||
Virial and Cubic EOS (11:18) (msu.edu)
1. To what region of pressure is the virial EOS limited at a given temperature? Why?
|08.02 - The Internal Energy Departure Function||Click here.||73.33329999999999||3||
The Internal Energy Departure Function (11min, uakron.edu) Deriving departure functions for a variety of equations of state is simplified by transforming to dimensionless units and using density instead of volume. This also leads to an extra simplification for the internal energy departure function.
1. What is the value of T(∂P/∂T)V - P for an ideal gas?
|13.05 - UNIFAC||Click here.||73.33329999999999||3||
UNIFAC concepts (8:17) (msu.edu)
UNIFAC is an extension of the UNIQUAC method where the residual contribution is predicted based on group contributions using energy parameters regressed from a large data set of mixtures. This screecast introduces the concepts used in model development. You may want to review group contribution methods before watching this presentation.
1. What is the difference between the upper case Θ of UNIFAC and the lower cast θ of UNIQUAC?
2. Suppose you had a mixture that was exactly the same proportions as the lower right "bubble" in slide 2. Compute ΘOH for that mixture.
3. Compare your value computed in 2 to the value given by unifac.xls.
|04.02 The Microscopic View of Entropy||Click here.||72||5||
Principles of Probability III, Distributions, Normalizing, Distribution Functions, Moments, Variance. This screencast extends beyond material covered in the textbook, but may be helpful if you study statistical mechanics in another course. (msu.edu, 15min) (Flash)
|13.01 - Local Composition Theory||Click here.||71.11109999999999||9||
Local Composition Concepts (6:51) (msu.edu)
The local composition models of chapter 13 share common features covered in this screencasts. An understanding of these principles will make all the algebra in the models less daunting.
1. In the picture of molecules given in the presentation on slide 2, what is the numerical value of the local composition x11?
|12.01 - The van der Waals Perspective for Mixtures||Click here.||70||4||
Mixing Rules (7:23) (msu.edu)
How should energy depend on composition? Should it be linear or non-linear? What does the van der Waals approach tell us about composition dependence? This screencasts shows that the mixing rule for 'a' in a random mixture should be quadratic. A linear mixing rule is usually used for the van der Waals size parameter.
|11.13 - Osmotic Pressure||Click here.||70||2||
MW of protein by osmotic pressure - (8:23) (learncheme.com)
An application of osmotic pressure measurement to determine MW of a protein.
|12.03 - Scatchard-Hildebrand Theory||Click here.||68.5714||7||
Scatchard-Hildebrand Theory (6:53) (msu.edu)
Have you ever heard 'Like dissolves like'? Here we see that numerically. The Scatchard-Hildebrand model builds on the van Laar equation by using pure component information. Scatchard and Hildebrand replaced the energy departure with the experimental energy of vaporization. Because this is related to the 'a' parameter in the van Laar theory, they developed a parameter called the 'solubility parameter', but based it on the energy of vaporization. Interestingly, the model reduces to the one parameter Margules equation when the molar volumes are the same.
1. Based on the Scatchard-Hildebrand model, arrange the following mixtures from most compatible to least compatible. (a) Pentane+hexane, (b) decane+decalin, (c) 1-hexene+dodecanol, (d) pyridine+methanol,
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