09.02 - The Clausius-Clapeyron Equation
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- Chapter 1 - Basic concepts
- Chapter 2 - The energy balance
- Chapter 3 - Energy balances for composite systems.
- Chapter 4 - Entropy
- Chapter 5 - Thermodynamics of Processes
- Chapter 6 - Classical Thermodynamics - Generalization to any Fluid
- Chapter 7 - Engineering Equations of State for PVT Properties
- Chapter 8 - Departure functions
-
Chapter 9 - Phase Equlibrium in a Pure Fluid
- 09.01 - Criteria for Phase Equilibrium
- 09.02 - The Clausius-Clapeyron Equation
- 09.03 - Shortcut Estimation of Saturation Properties
- 09.04 - Changes in Gibbs Energy with Pressure
- 09.05 - Fugacity and Fugacity Coefficient
- 09.06 - Fugacity Criteria for Phase Equilibria
- 09.07 - Calculation of Fugacity (Gases)
- 09.08 - Calculation of Fugacity (Liquids)
- 09.09 - Calculation of Fugacity (Solids)
- 09.10 - Saturation Conditions from an Equation of State
- 09.11 - Stable Roots and Saturation Conditions
- Chapter 10 - Introduction to Multicomponent Systems
- Chapter 11 - An Introduction to Activity Models
- Chapter 12 - Van der Waals Activity Models
- Chapter 13 - Local Composition Activity Models
- Chapter 14 - Liquid-liquid and solid-liquid equilibria
- Chapter 16 - Advanced Phase Diagrams
- Chapter 15 - Phase Equilibria in Mixtures by an Equation of State
- Chapter 17 - Reaction Equilibria
- Chapter 18 - Electrolyte Solutions
Estimating the Heat of Vaporization(3min)
Estimating the Heat of Vaporization from Antoine's Equation (3min, learncheme.com) The Clausius-Clapeyron equation shows that the heat of vaporization is slope of the vapor pressure curve. So you just need to differentiate the Antoine equation to estimate the heat of vaporization. This sample calculation shows how to compute the heat of vaporization of benzene given Antoine coefficients.
Comprehension Questions:
1. Estimate the vapor pressure (torr) of benzene at 55C using the equation given in the screencast.
2. Estimate (or report) the heat of vaporization (J/mol) of benzene according to the screencast.
3. Estimate the vapor pressure (torr) of benzene at 55C using the SCVP equation (2.47).
4. Estimate the heat of vaporization (J/mol) of benzene using the SCVP equation.
5. Estimate the heat of vaporization (J/mol) of benzene using Eq. 2.45.