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02.04 Lost Work Versus Reversibility
Book navigation
- Chapter 1 - Basic concepts
-
Chapter 2 - The energy balance
- 02.01 Expansion/Contraction Work
- 02.03 Work Associated with Flow
- 02.04 Lost Work Versus Reversibility
- 02.06 Path Properties and State Properties
- 02.07 The Closed-System Energy Balance
- 02.08 The Open-System, Steady-State Energy Balance
- 02.09 The Complete Energy Balance
- 02.10 Internal Energy, Enthalpy, and Heat Capacities
- 02.11 Reference States
- 02.13 Energy Balances for Process Equipment
- 02.15 Closed and Steady-State Open Systems
- 02.16 Unsteady State Open Systems
- 02.18 Chapter 2 Summary
- Chapter 3 - Energy balances for composite systems.
- Chapter 4 - Entropy
- Chapter 5 - Thermodynamics of Processes
- Chapter 6 - Classical Thermodynamics - Generalization to any Fluid
- Chapter 7 - Engineering Equations of State for PVT Properties
- Chapter 8 - Departure functions
- Chapter 9 - Phase Equlibrium in a Pure Fluid
- Chapter 10 - Introduction to Multicomponent Systems
- Chapter 11 - An Introduction to Activity Models
- Chapter 12 - Van der Waals Activity Models
- Chapter 13 - Local Composition Activity Models
- Chapter 14 - Liquid-liquid and solid-liquid equilibria
- Chapter 16 - Advanced Phase Diagrams
- Chapter 15 - Phase Equilibria in Mixtures by an Equation of State
- Chapter 17 - Reaction Equilibria
- Chapter 18 - Electrolyte Solutions
Reversibility
The reversible process is a common conception throughout discussions of thermodynamics. One very common illustration has to do with grains of sand being removed from a piston (KhanAcademy, 15min). It is also helpful to put the relation of reversibility into context with the work as a path function. (YouTube, 1.5min).
Comprehension Questions
1. Describe what happens when you knock a complete block off a piston under pressure. Assume the piston has mass roughly equal to the block, the cylinder is infinitely tall and everything is adiabatic, the gas in the cylinder is ideal, and the open side of the cylinder is at atmospheric pressure. In particular, does the piston go monotonically to its equilibrium position or does it do something else? If not, then what causes it to approach in a different way and why does it eventually reach its equilibrium state?
2. Consider the same piston/cylinder as above but compare it to a piston/cylinder with grains of sand. Is the final height of the piston the same, lower, or higher when you remove the weight one grain at a time vs. knocking the block off all at once? Hint: write the energy balance and carefully consider the work accomplished in each case.